19 Hydrogen Chloride (HCl) Properties(Explained for Beginners)

HCl properties: MW 36.46 g/mol. Colorless gas. Melting point -114.2°C, boiling point -85.1°C. Density 1.639 kg/m³ (gas, 0°C), 1.194 g/mL (liquid, 20°C). Vapor pressure 4.2 MPa (20°C). Viscosity 0.26 cP (-85°C). Heat capacity 29.12 J/mol•K. Forms hydrates HCl•H2O, HCl•2H2O, HCl•3H2O, HCl•6H2O. Conducts electricity in aqueous solution.

Hydrogen Chloride (HCl) Properties

HCL Basic Properties

PropertyValue
Atomic Number1 (H), 17 (Cl)
Atomic Mass36.46 g/mol
State at Room TemperatureGas
Density1.49 g/L (gas)
Electrons1 (H), 17 (Cl)
Protons1 (H), 17 (Cl)
Neutrons0 (H), 18-20 (Cl)
FamilyHydrogen, Halogens
Period1 (H), 3 (Cl)
DiscoveryDiscovered in 1810 by Humphry Davy
CostInexpensive to produce

HCL Physical Properties

PropertyValue
Melting Point-114°C
Boiling Point-85°C
SolubilityHighly soluble in water, forming hydrochloric acid
ConductivityPoor conductor of electricity
MagnetismNon-magnetic
ColorColorless
OdorPungent, irritating
HardnessN/A (gas)
Vapor Pressure40.1 atm at 20°C
Viscosity0.0089 cP at 0°C
Surface TensionN/A (gas)
Refractive Index1.000 (gas)
Specific Heat Capacity14.3 J/(mol·K)
Thermal ExpansionN/A (gas)

HCL Chemical Properties

PropertyValue
ReactivityHighly reactive, especially with bases and metals
FlammabilityNon-flammable
pH0 (aqueous solution)
Oxidation States-1
Electronegativity3.1 (Pauling scale)
Corrosion ResistanceHighly corrosive
Chemical StabilityStable under normal conditions
Heat of CombustionN/A (no combustion)
Rate of ReactionVaries depending on conditions
Acid-Base BehaviorStrong acid
Redox Potential+0.22 V (Cl2/Cl-)

HCL Spectroscopic Properties

PropertyValue
Absorption SpectrumCharacteristic absorption bands in the infrared region
Emission SpectrumCharacteristic emission lines in the visible and ultraviolet regions
NMR Properties1H NMR: δ = 0 ppm (reference)

HCL Crystallographic Properties

PropertyValue
Crystal StructureN/A (gas)
Unit Cell DimensionsN/A (gas)

HCL Electronic Properties

PropertyValue
Band GapN/A (gas)
Electrical ResistivityN/A (gas)

HCL Isotopic Composition

IsotopeAbundance
Hydrogen-1 (1H)99.9885%
Hydrogen-2 (2H, Deuterium)0.0115%
Hydrogen-3 (3H, Tritium)Trace amounts
Chlorine-35 (35Cl)75.78%
Chlorine-37 (37Cl)24.22%

HCL Discovery Details

Hydrogen chloride was first prepared in 1648 by Glauber by heating sodium chloride with concentrated sulfuric acid. Davy demonstrated in 1840 that HCl is a combination of chlorine and hydrogen.

Interesting Facts

  • Hydrogen chloride is a colorless gas with a pungent aroma.
  • It is highly soluble in water, forming hydrochloric acid.
  • Hydrochloric acid is commonly known as HCl and is used in various industrial applications.

HCL Applications

Industrial Uses

  • Production of hydrochloric acid for various chemical processes.
  • Used in the synthesis of compounds for water treatment chemicals.

Medical Uses

  • Utilized in pharmaceuticals and medical laboratories for chemical reactions.

Agricultural Uses

  • Additive in animal feed to enhance digestion processes.

Energy Production

  • Used in fuel cells for energy generation.

Technology and Electronics

  • Essential in the semiconductor industry as a cleaning and etching agent.
  • Catalyst in organic synthesis reactions.

Environmental Applications

  • Used as a disinfectant and in water treatment processes.

HCL Safety Precautions

HCL Safety Precautions
  • Hydrogen chloride is a highly corrosive gas that can cause severe burns to the eyes, skin, and respiratory system upon exposure.
  • Proper personal protective equipment like goggles, gloves, and a respirator should be worn when handling HCl.
  • Exposure to high concentrations of hydrogen chloride can be fatal, necessitating well-ventilated areas or local exhaust ventilation during use.
  • Hydrochloric acid is usually sold as a solution containing 28–35% hydrogen chloride by weight.
  • Anhydrous liquid hydrogen chloride is available but has limited applications due to storage challenges.

References:

Wiki-Periodic_table

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